Eco-Friendly Adsorbent to Removal Heavy Metal using Melissa officinalis Extraction -@Diethanolamine from aqueous solution
DOI:
https://doi.org/10.64354/rgfgrf91Keywords:
: Melissa officinalis L; methanol extract (MEIG); Manganese ions; adsorptive removal; functionalized Diethanolamine.Abstract
This study, using environmentally friendly bio adsorbents to purge industrial wastewater of heavy metal ions is an effective strategy. However, Melissa officinalis L. is used to remove manganese ions. No research has been conducted on its methanol extract (MEIG). To remove harmful manganese ions from aqueous solutions, leave of the plant were studied as bio adsorbents in a batch adsorption model. To determine the optimal conditions, intermittent adsorption tests were performed. Adsorption occurred rapidly, taking 90 minutes to reach equilibrium. In order to remove harmful manganese ions from aqueous solutions, portions of the plant were studied as bio adsorbents in a batch adsorption model. To find the ideal circumstances, intermittent adsorption tests were carried out. Adsorption happened quickly; it took 90 minutes to reach equilibrium. To optimize the procedure, the effects of time, dosage, concentration, and pH were methodically examined. After 90 minutes, the maximum removal rates of manganese ions from equilibrium were 94.05% under ideal circumstances for efficiently eliminating lead ions (Mn) from aqueous solutions. utilizing an R2 value of 0.9905 the Langmuir model with and Melissa officinalis Extraction -@Diethanolamine. Following characterization, N-H stretching appeared around 3290.The alcoholic extract of Melissa officinalis was shown to have a varied chemical composition using gas chromatography-mass spectrometry (GC-MS).
References
[1] Saxena V. Water quality, air pollution, and climate change: investigating the environmental impacts of industrialization and urbanization. Water, Air, & Soil Pollution. 2025;236:73. https://doi.org/10.1007/s11270-024-07702-4
[2] Faili NT, Burghal KS. Preparation and evaluation of waste ground tyre rubber as antioxidant, antibacterial activity and anticorrosion inhibitor for N80 steel in 0.1 N H3PO4. Baghdad Science Journal. 2024;21:1. https://doi.org/10.21123/bsj.2023.6038
[3] Mandal W, Fajal S, Desai AV, Ghosh SK. Metal-organic frameworks (MOFs) and related other advanced porous materials for sequestration of heavy metal-based toxic oxo-pollutants from water. Coordination Chemistry Reviews. 2025;524:216326. https://doi.org/10.1016/j.ccr.2024.216326
[4] Das S, Sultana KW, Ndhlala AR, Mondal M, Chandra I. Heavy metal pollution in the environment and its impact on health: exploring green technology for remediation. Environmental Health Insights. 2023;17:11786302231201259. https://doi.org/10.1177/11786302231201259
[5] Burghal KS. A review of removing pesticides and their impact on the environment. Humanities & Natural Sciences Journal. 2025;6:108–122. https://doi.org/10.53796/hnsj612/9
[6] Yang Y, Wang Y, Xue C, Lin Y, Lee JF, Yi X, Dang Z. Efficient removal of heavy metals from acid mine drainage by ε-MnO2 adsorption. Journal of Cleaner Production. 2024;452:141936. https://doi.org/10.1016/j.jclepro.2024.141936
[7] Huang Q, Wan J, Nan W, Li S, He B, Peng Z. Association between manganese exposure in heavy metals mixtures and the prevalence of sarcopenia in US adults from NHANES 2011–2018. Journal of Hazardous Materials. 2024;464:133005. https://doi.org/10.1016/j.jhazmat.2023.133005
[8] Dey S, Tripathy B, Kumar MS, Das AP. Ecotoxicological consequences of manganese mining pollutants and their biological remediation. Environmental Chemistry and Ecotoxicology. 2023;5:55–61. https://doi.org/10.1016/j.enceco.2023.01.001
[9] Kandel DR, Poudel MB, Radoor S, Chang S, Lee J. Decoration of dandelion-like manganese-doped iron oxide microflowers on plasma-treated biochar for alleviation of heavy metal pollution in water. Chemosphere. 2024;357:141757. https://doi.org/10.1016/j.chemosphere.2024.141757
[10] Alsaeed RD, Aldarwish A, Khouri L, Kolluru V. Response surface modeling of sodium hypochlorite-based manganese oxidation in drinking water. DYSONA–Applied Science. 2025;6:334–342. https://doi.org/10.30493/DAS.2025.484126
[11] Hussain M, Ali AS, Kousar T, Mahmood F, Haruna A, Zango ZU, Adamu H, Kotp MG, Abdulganiyyu IA, Keshta BE. Efficient removal of manganese (II) ions from aqueous solution using biosorbent derived from rice husk. Sustainable Chemistry One World. 2025;5:100047. https://doi.org/10.1016/j.scowo.2025.100047
[12] Singh N, Shah K, Pramanik BK. Synthesis and application of manganese-doped zinc oxide as a potential adsorbent for removal of Congo red dye from wastewater. Environmental Research. 2023;233:116484. https://doi.org/10.1016/j.envres.2023.116484
[13] Akhtar MS, Ali S, Zaman W. Innovative adsorbents for pollutant removal: exploring the latest research and applications. Molecules. 2024;29:4317. https://doi.org/10.3390/molecules29184317
[14] Lobach AR, Schmidt F, Fedrizzi D, Müller S. Toxicological safety evaluation of an aqueous lemon balm (Melissa officinalis) extract. Food and Chemical Toxicology. 2024;187:114565. https://doi.org/10.1016/j.fct.2024.114565
[15] Fatemi F, Zamany M, Farahmand S, Dini S. Phytochemical and toxicological analyses of herbal mixtures containing Hypericum perforatum and Melissa officinalis. Turkish Journal of Pharmaceutical Sciences. 2024;21:340. https://doi.org/10.4274/tjps.galenos.2023.28092
[16] Silva BN, Cadavez V, Caleja C, Pereira E, Calhelha RC, Añibarro-Ortega M, Finimundy T, Kostić M, Soković M, Teixeira JA. Phytochemical composition and bioactive potential of Melissa officinalis L., Salvia officinalis L. and Mentha spicata L. extracts. Foods. 2023;12:947. https://doi.org/10.3390/foods12050947
[17] Zam W, Quispe C, Sharifi-Rad J, López MD, Schoebitz M, Martorell M, Sharopov F, Fokou PVT, Mishra AP, Chandran D. An updated review on the properties of Melissa officinalis L.: not exclusively anti-anxiety. Frontiers in Bioscience-Scholar. 2022;14:16. https://doi.org/10.31083/j.fbs1402016
[18] Huang Y, Duan Z, Li C, Qiu T. Preparation of Cu-Ni/ZrO2 and Cu/ZrO2-Co3O4 catalysts by co-precipitation-hydrazine hydrate reduction method and their efficient dehydrogenation mechanism for diethanolamine. Journal of Alloys and Compounds. 2025;1030:180952. https://doi.org/10.1016/j.jallcom.2025.180952
[19] Ji X, Liu Y, Gao Z, Lin H, Xu X, Zhang Y, Zhu K, Zhang Y, Sun H, Duan J. Efficiency and mechanism of adsorption for imidacloprid removal from water by Fe-Mg co-modified water hyacinth-based biochar: batch adsorption, fixed-bed adsorption, and DFT calculation. Separation and Purification Technology. 2024;330:125235. https://doi.org/10.1016/j.seppur.2023.125235
[20] Ismail UM, Onaizi SA, Vohra MS. Crystal violet removal using ZIF-60: batch adsorption studies, mechanistic and machine learning modeling. Environmental Technology & Innovation. 2024;33:103456. https://doi.org/10.1016/j.eti.2023.103456
[21] Shi L, Zhao W, Yang Z, Subbiah V, Suleria HAR. Extraction and characterization of phenolic compounds and their potential antioxidant activities. Environmental Science and Pollution Research. 2022;29:81112–81129. https://doi.org/10.1007/s11356-022-23337-6
[22] Liu R, Wu K, Sun X, Liu Y, Wang Y, Liu J, Li Z. Insights into the stability assessment and reaction mechanisms of Mn-oxide-containing adsorbents for As(III) removal in filter columns: migration laws and stabilization mechanisms of Mn element. Journal of Hazardous Materials. 2025;483:136526. https://doi.org/10.1016/j.jhazmat.2024.136526
[23] Melaku AZ. Removal of manganese from wastewater using Moringa stenopetala plant parts as an adsorbent material. Heliyon. 2023;9:e22517. https://doi.org/10.1016/j.heliyon.2023.e22517
[24] Wu W, Zhang J, Zhu W, Zhao S, Gao Y, Li Y, Ding L, Ding H. Novel manganese and nitrogen co-doped biochar based on sodium bicarbonate activation for efficient removal of bisphenol A: mechanism insight and role analysis of manganese and nitrogen by combination of characterizations, experiments and density functional theory calculations. Bioresource Technology. 2024;399:130608. https://doi.org/10.1016/j.biortech.2024.130608
[25] Jeppu A, Girish G, Prabhu CR, Mayer K. Multi-component adsorption isotherms: review and modeling studies. Environmental Processes. 2023;10(2):38. https://doi.org/10.1007/s40710-023-00631-0
[26] Topare NS, Wadgaonkar VS. A review on application of low-cost adsorbents for heavy metals removal from wastewater. Materials Today: Proceedings. 2023;77:8–18. https://doi.org/10.1016/j.matpr.2022.08.450
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